3EC1 - APPLIED CHEMISTRY |
Units: I |
Electrochemistry: Specific, equivalent and molecular conductance, their
determination, theories of electrolytic conductance, Debye-Huckle theory of strong
electrolytes, galvanic cells, reference electrodes and their potentials. Standard cell,
standard electrode potential, determination of dissociation constants of acids and
bases, solubility product, hydrolysis constant, hydrogen ion concentration, complex
formation, activity of electrolytes etc., theory of acid-base indicators, electrometric
titrations.
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Units: II |
Photochemistry: Photochemical Reactions, Laws of Photochemistry.
Reactions and their Mechanism: Types of mechanism, types of reactions and method of
determination of mechanism. |
Units: III |
Chemical Bonding: Basic concepts of bonding. Types of bonding, covalent bonding,
multiple bonding, inductive and field effects and bond energy. Aromaticity and Huckle’s
rule of electrons, Hyperconjugation and Tautomerism, Bonding weaker than covalent,
resonance and field effects.
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Units: IV |
Aromatic Chemistry: Structure of benzene resonance and orbital picture, Orientation and
directive influence of substituents.
Heterocyclic Compounds: Heterocyclic compounds containing one heteroatom, pyrole,
thiophene, furan, pyridine. Their aromatic character.
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Units: V |
Carbohydrates: Introduction, definition and classification, structure of glucose and
fructose.
Stereochemistry: A brief account of stereochemistry, optical activity and chirality,
configuration and strain.
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Text/ Reference Books |
1. Jerry March, “Organic Chemistry,” John Wiley, New York.
2. Finar, I. L.,“Organic Chemistry,” ELBS, New Delhi.
3. Morrison and Boyd, “Organic Chemistry,” MacMillan.
4. Glasstone, S., “A Textbook of Physical Chemistry,” MacMillan.
5. Bahl and Tuli, “Essentials of Physical Chemistry,” S. Chand and Co.
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