CH 2251-PHYSICAL CHEMISTRY |
CHEMICAL KINETICS |
Rate equations order of reaction I order II order III order zero order pseudo order reactions effect of temperature on reaction rate concept of activation energy- chain reactions branched chain reactions reactions in solutions influence of ionic strength in rates of reactions. |
ELECTROCHEMISTRY |
Electrolytic conductance specific conductance equivalent conductance molar conductance-variation with dilution kohlrausch's law- applications of kohlrausch's law - molar ionic conductance - conductometric titrations ostwald dilution law Debye Huckel theory of mean ionic activity coefficient.
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PHASE RULE AND DISTRIBUTION LAW |
Definition of terms- one component system water sulphur two component system simple eutectic system reduced phase rule. Distribution-chemical combinations-applications-applications of distribution law-Raoults law-Henry's law-ideal and non-ideal solutions-vapour pressure & boiling point |
SURFACE CHEMISTRY |
ADSORPTION
Definition types isotherms theories of adsorption BET method applications.
CATALYSIS
Homogeneous catalysis acid base enzyme catalysis autocatalysis mechanism and kinetics Michaelis-Menten equation - Heterogeneous catalysis kinetics effect of temperature on surface reactions |
MACRO MOLECULES |
COLLOIDS
Classification preparations coagulation flocculation determination of size of particles- surfactants emulsions emulsifiers gels applications.
POLYMERS
Classification polymerization reactions molar masses of reactions determination of molar masses- kinetic study.
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REFERENCE |
Text Books |
1. Puri B.H and Sharma L.R. Principles of Physical Chemistry, S. Nagin Chand and Company, Delhi (1994)
2. P.L.Soni , O.P. Dharmarha & U.N. Dash, Textbook of Physical Chemistry , Sultan Chand & Sons. |
Reference Books |
1. Kund and Jain, Physical Chemistry, S.Chand and Company, Delhi (1996)
2. Kuriakose, J.C. and Rajaram J, Chemistry in Engineering and Technology Vol. I, Tata McGraw-Hills.1984. |